The Exchange Client Throttling Policies only can be changed via powershell. To change the OWA concurrent connection we can use the below command.
Set-ThrottlingPolicy -Identity DefaultThrottlingPolicy_0333f596-4e99-435b-aa0c-2723ff3af6fe –OWAMaxConcurrency1000
To view all the Throttling Policies settings, you can use “Get-ThrottlingPolicy” command
Understanding Client Throttling Policies
http://technet.microsoft.com/en-us/library/dd297964.aspx
Set-ThrottlingPolicy
http://technet.microsoft.com/en-us/library/dd298094.aspx