配置文件

<!--邮件提醒-->

  <add key="MailAlertEnable" value="0" />

<add key="FromMail" value="njmtltrack@conmet.com.cn" />

<add key="ToMail" value="mengyuan@163.com;yingyingu@qq.com" />

<add key="SendMailUri" value="http://192.168.1.1:8080/SystemMaintainService.svc/SendExternalMail" />

实现类

public class SendOutMail
    {
        private static string mailuri = System.Configuration.ConfigurationManager.AppSettings["SendMailUri"];
        public static void SendMailByMesWcf(string FromMial, string ToMial, string Subject, string Body)
        {
            Dictionary<string, string> mail = new Dictionary<string, string>();
            mail.Add("FromMail", FromMial);
            mail.Add("ToMail", ToMial);
            mail.Add("Subject", Subject);
            mail.Add("Body", Body);

            //序列化将要传输的对象
            var requestJson = Newtonsoft.Json.JsonConvert.SerializeObject(mail);
            //构建HttpClient对象
            HttpClient httpClient = new HttpClient();
            //设置将要赋值的对象
            HttpContent httpContent = new StringContent(requestJson);
            //设置消息头
            httpContent.Headers.ContentType = new MediaTypeHeaderValue("application/json");
            //异步发送请求
            //httpClient.PostAsync(mailuri, httpContent);
            var events = httpClient.PostAsync(mailuri, httpContent).Result;
            //异步获取请求的结果
            var result = events.Content.ReadAsStringAsync().Result;

        }

        /// <summary>
        /// 发送邮件方法
        /// </summary>
        /// <param name="FromMial">发件人邮箱</param>
        /// <param name="ToMial">收件人邮箱(多个收件人地址用";"号隔开)</param>
        /// <param name="AuthorizationCode">发件人授权码</param>
        /// <param name="ReplyTo">对方回复邮件时默认的接收地址(不设置也是可以的)</param>
        /// <param name="CCMial">//邮件的抄送者(多个抄送人用";"号隔开)</param>
        /// <param name="File_Path">附件的地址</param>
        public static void SendMail(string FromMial, string ToMial, string AuthorizationCode, string ReplyTo, string CCMial, string File_Path, string Subject, string Body)
        {
            try
            {
                //实例化一个发送邮件类。
                MailMessage mailMessage = new MailMessage();

                //邮件的优先级,分为 Low, Normal, High,通常用 Normal即可
                mailMessage.Priority = MailPriority.Normal;

                //发件人邮箱地址。
                mailMessage.From = new MailAddress(FromMial);

                //收件人邮箱地址。需要群发就写多个
                //拆分邮箱地址
                List<string> ToMiallist = ToMial.Split(';').ToList();
                for (int i = 0; i < ToMiallist.Count; i++)
                {
                    mailMessage.To.Add(new MailAddress(ToMiallist[i]));  //收件人邮箱地址。
                }

                if (ReplyTo == "" || ReplyTo == null)
                {
                    ReplyTo = FromMial;
                }

                //对方回复邮件时默认的接收地址(不设置也是可以的哟)
                mailMessage.ReplyTo = new MailAddress(ReplyTo);

                if (CCMial != "" && CCMial != null)
                {
                    List<string> CCMiallist = ToMial.Split(';').ToList();
                    for (int i = 0; i < CCMiallist.Count; i++)
                    {
                        //邮件的抄送者,支持群发
                        mailMessage.CC.Add(new MailAddress(CCMial));
                    }
                }
                //如果你的邮件标题包含中文,这里一定要指定,否则对方收到的极有可能是乱码。
                mailMessage.SubjectEncoding = Encoding.GetEncoding(936);

                //邮件正文是否是HTML格式
                mailMessage.IsBodyHtml = false;

                //邮件标题。
                mailMessage.Subject = Subject;
                //邮件内容。
                mailMessage.Body = Body;

                //设置邮件的附件,将在客户端选择的附件先上传到服务器保存一个,然后加入到mail中  
                if (File_Path != "" && File_Path != null)
                {
                    //将附件添加到邮件
                    mailMessage.Attachments.Add(new Attachment(File_Path));
                    //获取或设置此电子邮件的发送通知。
                    mailMessage.DeliveryNotificationOptions = DeliveryNotificationOptions.OnSuccess;
                }

                //实例化一个SmtpClient类。
                SmtpClient client = new SmtpClient();

                #region 设置邮件服务器地址

                //在这里我使用的是163邮箱,所以是smtp.163.com,如果你使用的是qq邮箱,那么就是smtp.qq.com。
                // client.Host = "smtp.163.com";
                client.EnableSsl = true;
                if (FromMial.Length != 0)
                {
                    //根据发件人的邮件地址判断发件服务器地址   默认端口一般是25
                    string[] addressor = FromMial.Trim().Split(new Char[] { '@', '.' });
                    switch (addressor[1])
                    {
                        case "conmet":
                            client.Host = "smtp.conmet.cn";
                            client.EnableSsl = false;
                            break;
                        case "163":
                            client.Host = "smtp.163.com";
                            break;
                        case "126":
                            client.Host = "smtp.126.com";
                            break;
                        case "qq":
                            client.Host = "smtp.qq.com";
                            break;
                        case "gmail":
                            client.Host = "smtp.gmail.com";
                            break;
                        case "hotmail":
                            client.Host = "smtp.live.com";//outlook邮箱
                            //client.Port = 587;
                            break;
                        case "foxmail":
                            client.Host = "smtp.foxmail.com";
                            break;
                        case "sina":
                            client.Host = "smtp.sina.com.cn";
                            break;
                        default:
                            client.Host = "smtp.exmail.qq.com";//qq企业邮箱
                            break;
                    }
                }
                #endregion

                
                
                //不和请求一块发送。
                client.UseDefaultCredentials = false;
                if (string.IsNullOrEmpty(AuthorizationCode) == false)
                {
                    //验证发件人身份(发件人的邮箱,邮箱里的生成授权码);
                    client.Credentials = new NetworkCredential(FromMial, AuthorizationCode);
                }
                //如果发送失败,SMTP 服务器将发送 失败邮件告诉我  
                mailMessage.DeliveryNotificationOptions = DeliveryNotificationOptions.OnFailure;
                //发送
                client.Send(mailMessage);
                Console.WriteLine("发送成功");
            }
            catch (Exception ex)
            {
                Console.WriteLine("发送失败");
            }
        }

调用

SendOutMail.SendMailByMesWcf(FromMail, ToMail, txtLineName.Text + "系统报警" + DateTime.Now.ToString(), ex.ErrMessage);