1、查看网卡信息

ip addr
1: lo: <LOOPBACK,UP,LOWER_UP> mtu 16436 qdisc noqueue state UNKNOWN 
    link/loopback 00:00:00:00:00:00 brd 00:00:00:00:00:00
    inet 127.0.0.1/8 scope host lo
    inet6 ::1/128 scope host 
       valid_lft forever preferred_lft forever
2: eth0: <BROADCAST,MULTICAST,UP,LOWER_UP> mtu 1500 qdisc pfifo_fast state UP qlen 1000
    link/ether 00:0c:29:0a:69:59 brd ff:ff:ff:ff:ff:ff
    inet 192.168.100.162/24 brd 192.168.100.255 scope global eth0
    inet6 fe80::20c:29ff:fe0a:6959/64 scope link 
       valid_lft forever preferred_lft forever
3: eth1: <BROADCAST,MULTICAST> mtu 1500 qdisc noop state DOWN qlen 1000
    link/ether 00:0c:29:0a:69:63 brd ff:ff:ff:ff:ff:ff

2、复制配置文件,并修改DEVICE、IPADDR和HWADDR

cd /etc/sysconfig/network-scripts/
cp ifcfg-eth0 ifcfg-eth1
cat ifcfg-eth0
DEVICE=eth0
TYPE=Ethernet
UUID=c9c43a0d-439b-4855-9058-56edf186bf74
ONBOOT=yes
NM_CONTROLLED=yes
BOOTPROTO=none
IPADDR=192.168.100.162
PREFIX=24
GATEWAY=192.168.100.1
DEFROUTE=yes
IPV4_FAILURE_FATAL=yes
IPV6INIT=no
NAME="System eth0"
HWADDR=00:0C:29:0A:69:59
LAST_CONNECT=1446137377

vim ifcfg-eth1
DEVICE=eth1
TYPE=Ethernet
UUID=c9c43a0d-439b-4855-9058-56edf186bf74
ONBOOT=yes
NM_CONTROLLED=yes
BOOTPROTO=none
IPADDR=192.168.100.163
PREFIX=24
GATEWAY=192.168.100.1
DEFROUTE=yes
IPV4_FAILURE_FATAL=yes
IPV6INIT=no
NAME="System eth1"
HWADDR=00:0c:29:0a:69:63
LAST_CONNECT=1446137377

3、重启网络服务

service network restart