You can also configure it using aws configure or if already executed you can identify it in ~/.aws/config. Example:

[default]
region=us-east-1

The regions are as follows. See second column.

$ ec2-describe-regions
REGION  eu-central-1    ec2.eu-central-1.amazonaws.com
REGION  sa-east-1   ec2.sa-east-1.amazonaws.com
REGION  ap-northeast-1  ec2.ap-northeast-1.amazonaws.com
REGION  eu-west-1   ec2.eu-west-1.amazonaws.com
REGION  us-east-1   ec2.us-east-1.amazonaws.com
REGION  us-west-1   ec2.us-west-1.amazonaws.com
REGION  us-west-2   ec2.us-west-2.amazonaws.com
REGION  ap-southeast-2  ec2.ap-southeast-2.amazonaws.com
REGION  ap-southeast-1  ec2.ap-southeast-1.amazonaws.com